Daniela Hohenstern
Institute of Forest Ecosystems

Alfred-Möller-Straße 1, Haus 41/42
16225 Eberswalde
Phone: +49 3334 3820 300
Fax: +49 3334 3820 354

Contact persons for

CL Validation


Figure 2: (c) Cornelius Oertel
Results of weathering rate modelling with PROFILE (© Cornelius Oertel)

Validation of the national modelling of critical loads

Background and Objective

Critical Loads (CL) were established to counteract the increased nitrogen (N) and sulfur inputs (S) and their harmful impact on forest ecosystems. It determines limits for the deposition of nitrogen and sulfur which require obligatory measures to decrease the emissions and to protect forests against acidification and eutrophication.

The calculation of CL occurs through empirical studies, simple mass balances according to the steady-state-principle or dynamic models which are shown in the Mapping Manual UN/ECE 2017 and the national report.

The processes of denitrification and weathering are of high importance for the calculation of CL and were evaluated in this project.

Denitrification defines the reduction of nitrate (NO3-) and nitrite (NO2-) to laughing gas (N2O), nitrogen monoxide (NO) and molecular nitrogen (N2) (Groffman et al., 2006).

Hence, the denitrification leads to a loss of nitrogen in the soil and the release of climate-relevant trace gases.

Both the weathering and the deposition are the reproducing forces regarding nutrients. The rate of weathering requires the buffering capacity and fertility of the soil and it is a criterion to assess the material sustainability in forestry. The weathering process is the highest sink for protons in the soil and it significantly influences the sensitivity of an ecosystem to acid inputs (Whitfield et al., 2006).

Both the modeling of the weathering rate and the amount of nitrogen released by denitrification are subject to large insecurities. This also effects the calculation of CL for acidification and eutrophication.

In this project, denitrification and the weathering were evaluated in terms of the CL calculation basis.


The denitrification part is composed of a literature study as well as laboratory tests about N2O and N2-emissions of forest soils.  The literature review evaluated 325 studies of N2O emissions and 80 studies of N2 emissions. The focus lies on the following criteria: ecosystems, climate zones, forest types, elevations, air/incubation temperature, precipitation/soil moisture, clay content, pH-value as well as carbon and nitrogen content in the soil.

The soil samples for the laboratory tests originate from the 16 nationwide distributed forest monitoring stations. 250 cm³ soil sampling rings are used for the analysis of N2O, methane (CH4) and CO2 emissions in the laboratory.

The analyses were performed at different levels of soil moisture (70 and 90% WFPS) and soil temperature (5, 15, and 20°C). At the same time, it is differentiated between disturbed and undisturbed samples.

Additionally, the impact of the clay content, the N-deposition as well as the NO3- and NH4+ content on the emissions has been investigated.

For the determination of the weathering rate the results from the x-ray fluorescence analysis of the Clay Mineral Consultation from the years 1989 to 2012 was used.

The reaction of the minerals with the elements of the soil solution has been calculated with the model PROFILE for every horizon separately. Climate data, deposition data, litterfall, element uptake by vegetation, soil parameters and the chemical composition of the soil solution are used for this purpose.



The comparison of the N2O literature review shows further need of denitrification measurements. The main share of the reviewed studies was made more than 10 years ago and does not meet the required quality standards for their measurement methods. In frequent cases the duration of the studies has been too short or the measurement intervals have been too large to receive significant results and comparisons.

Comparing the studies according to the classified criteria, the lack of studies for individual variables is noticeable, such as the clay content of > 62,5 % (only 2 studies), which makes an analysis of the dependence of denitrification on the investigated criterion impossible. This becomes particularly clear when only considering the studies rated as qualitatively good and very good.

The laboratory analysis about soil degassing only showed significant N2O emission results for disturbed soil samples with the treatment of 20°C and 90 % WFPS (Figure 1). In this case, the NO3 content in the soil showed a significant positive influence on N2O emissions. This becomes especially clear at the sites Conventwald (32,15 ± 29,65 kg N ha-1a-1) in the Black Forest near France as well as Tannenbusch (40,32 ± 37,09 kg N ha-1a-1) and Schwaney (77,29 ± 24,50 kg N ha-1a-1) (20-90-G) in North Rhine-Westphalia near the agriculturally intensive regions in the Netherlands (Figure 1). The emissions of the disturbed samples can be considered as the maximum potential of emissions. For the usage of undisturbed samples, as they appear naturally, the N2O emissions are less than 1 kg N ha-1a-1.

The CO2 emissions do not show any correlation to the N2O emissions. They are between 0,24 ± 0,04 µmol m-2s-1 (Tannenbusch) and 1,35 ± 0,65 µmol m-2s-1 (Colditz) for disturbed and from 0,34 ± 0,08 µmol m-2s-1 (Possen) to 1,29 ± 0,46 µmol m-2s-1 (Klingenthal) for undisturbed samples.

For CO2 and CH4 emissions, no correlation to the parameters clay content, nitrogen deposition, and NO3 and NH4 content can be observed. CH4 emissions in disturbed samples (20 °C, 90 % WFPS) range from -0.2 ± 0.01 µmol m-2 h-1 in Tannenbusch to

-11.93 ± 1.73 µmol m-2 h-1 in Colditz. The undisturbed samples provide CH4 emissions ranging from -0.08 ± 0.01 µmol m-2h-1 in Tannenbusch to -19.61 ± 1.86 µmol m-2h-1 in Colditz. Negative values here represent an uptake of CH4.

The calculation of the weathering rate shows that soils with a rough texture (clay <°18°mass-%) there are no significant differences for acid parent material (weathering class 1, n=59), as well as neutral and alkaline parent material (weathering class 2, n=20)

The calculation of the weathering rate shows that the rate of weathering is increasing with its class. (VW). For soils with a coarse texture and acidic (VW=1) or intermediate parent rock (VW=2) the median of 1,2 resp. 2,4 eq ha-1 a-1 cm-1 is way lower than the substrate-texture-approach of 2,5 and 7,5 eq ha-1 a-1 cm-1. Soils with a medium texture have medians of 6,5 for acidic (VW=3), 7,7 for intermediate (VW=4) and 14,9 eq ha-1 a-1 cm-1 for alkaline parent rock (VW=5). The main share of soils investigated are assigned to weathering classes 4 (n=191) and 1 (n=82) which are more than 70 %. The results for the weathering rate of fine or very fine texture are not significant as it is based on only 5 investigated forest soils.

For the soils of weathering classes 1 to 4 and 6, K-feldspar, plagioclase and illite provide the largest proportion of minerals (67-83 %) in the weathering rate. The proportion of illite increases with increasing weathering class, while the proportion of K-feldspar decreases. In soils of weathering class 5, pyrobole and in weathering rate 20 calcite and dolomite provide the highest proportion of minerals in the weathering rate.

The studies have shown that further investigations and measurements are needed to gain more significant results. For further research we recommend:

  • measurements of N2O and N2 emissions have to be conducted under unique conditions and requirements as well as specifying the measurement and site conditions
  • studies on denitrification must be extended to organic soils, as high N losses are to be expected here compared to mineral soils, especially in the degraded state.
  • further calculations with 3 independent methods for estimating the weathering rate


Involved Thünen-Partners

Involved external Thünen-Partners

Funding Body

  • Umweltbundesamt (UBA)
    (national, öffentlich)


1.2018 - 3.2021